Pentamethylcyclopentadienyl and cyclopentadienyl tantalum and niobium calixarene compounds and their water and acetonitrile inclusion complexes
- Massachusetts Institute of Technology, Cambridge, MA (United States)
Several niobium and tantalum pentamethylcyclopentadienyl or cyclopentadienyl calixarene complexes were prepared and structurally characterized. The cavity in these compounds is of an appropriate geometry to receive small molecules such as water or acetonitrile. X-ray diffraction and Fenske-Hall calculations were used in the consideration of the structure of these compounds.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 458746
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 10 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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