Reactivity of aliphatic amines toward platinum(II) complexes
- Universita di Messina (Italy); and others
Reaction kinetics for the displacement of 5-aminoquinoline (5-Aq) and diethyl sulfide (SEt{sub 2}) from cis-[PtPh{sub 2}(CO)(L)] (L = 5-Aq or SEt{sub 2}) by aliphatic amines was measured for a wide array of amines. Reaction products were characterized by IR and NMR spectroscopies and crystalk structures of selected products were reported. Steric effects on the substitutions were discussed.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 457879
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 18 Vol. 33; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
Similar Records
Reactivity of the carbonate radical toward metal complexes in aqueous solution
THE REACTION OF NIOBIUM(V) AND TANTALUM(V) HALIDES WITH ALIPHATIC AMINES
Reactivity of aliphatic nitriles toward hydrogenation on a nickel catalyst
Journal Article
·
Wed Dec 13 23:00:00 EST 1978
· J. Phys. Chem.; (United States)
·
OSTI ID:6141256
THE REACTION OF NIOBIUM(V) AND TANTALUM(V) HALIDES WITH ALIPHATIC AMINES
Journal Article
·
Wed Jan 31 23:00:00 EST 1962
· J. Less-Common Metals
·
OSTI ID:4797173
Reactivity of aliphatic nitriles toward hydrogenation on a nickel catalyst
Journal Article
·
Wed Nov 30 23:00:00 EST 1988
· Kinet. Catal. (Engl. Transl.); (United States)
·
OSTI ID:6093763