Platinum-gold cluster catalysts for D{sub 2}(gas)/H{sub 2}O(liquid) isotope exchange
- Univ. of Minnesota, Minneapolis, MA (United States)
The authors developed a homogeneous catalytic system for exchange of deuterium onto water. Platinum-gold phosphine cations catylze this exchange in pyridine. The authors probed these reactions kinetically and studied the catalysts by NMR allowing them to propose a reaction mechanism.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 457872
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 18 Vol. 33; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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