Dihydrogen activation by mixed platinum- and palladium-gold cluster compounds. Homogeneous catalytic H{sub 2}-D{sub 2} equilibration
- Univ. of Minnesota, Minneapolis, MN (United States)
Platinum- and palladium-gold cluster compounds were evaluated with respect to their ability to catalyze H{sub 2}-D{sub 2} equilibration. In addition, these phosphine-stabilized complexes were structurally characterized. Mechanistic studies for this reaction were performed by kinetic and spectroscopic analysis. The catalytic reaction appears to occur in three steps, which were determined.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 420965
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 17 Vol. 33; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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