La{sub 4}Ti{sub 5}Si{sub 4-x}P{sub x}O{sub 22} (x = 0, 1): A new family of two-dimensional solids. Synthesis and structure of the first member (m = 1) of the mixed-valence titanium(III/IV) oxosilicate series, La{sub 4}Ti(Si{sub 2}O{sub 7}){sub 2}(TiO{sub 2}){sub 4m}
- Rice Univ., Houston, TX (United States)
The authors report concerning the synthesis and structure of a series of oxosilicate and mixed-oxosilicophosphate compounds of the formula: La{sub 4}Ti{sub 5}Si{sub 4{minus}x}P{sub x}O{sub 22} (x = 0,1). The structure of these complexes was studied by X-ray diffraction. Four-probe electrical conductivity measurements are reported from 13 to 90 K. The structural and conductivity data are correlated.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 457130
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 1 Vol. 34; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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