Estimation of Arrhenius parameters for the 1,1 elimination of H{sub 2} from Si{sub 2}H{sub 6} and the role of chemically activated disilane in silane pyrolysis
Journal Article
·
· Journal of Physical Chemistry
- Univ. of Minnesota, Minneapolis, MN (United States)
This paper analyzes the Arrhenius parameters for the 1,1 H{sub 2} dissociation channel reaction rate for the disilane thermal decomposition. The RRKM model is used to estimate these arrhenius parameters. The role that chemically active disilane plays in the pyrolysis of silanes is also discussed. The estimate of the heat of formation of H{sub 3}SiSiH is determined also.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 456989
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 19 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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