Determination of the arrhenius parameters for Si{sub 2}H{sub 6} {l_reversible} SiH{sub 4} + SiH{sub 2} and {Delta}H{degrees} {sub f}(SiH{sub 2}) by RRKM analysis of forward and reverse reaction rate data
Journal Article
·
· Journal of Physical Chemistry
- Univ. of Minnesota, Minneapolis, MN (United States)
RRKM theory is used to generate good estimates of the high-pressure Arrhenius parameters for the thermal decomposition of disilane. The heat of formation of SiH{sub 2} is determined by this process to be 64.4 +- 1.0 kcal/mol.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 456988
- Journal Information:
- Journal of Physical Chemistry, Journal Name: Journal of Physical Chemistry Journal Issue: 19 Vol. 96; ISSN JPCHAX; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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