$gamma$-radiolysis of pure acyl chlorides at 77$sup 0$K: an electron spin resonance study of intermediate radicals

Journal Article · Mon Jan 01 04:00:00 EST 1973 · J. Chem. Soc., B, no. 11, pp. 1563-1565

OSTI ID:4425187

Faucitano, A; Martinotti, F F

The matrix isolation technique, using ESR spectroscopy, was used to investigate the nature of free radical intermediates of the gamma -radiolysis of polycrystalline linear and branched acyl chlorldes at 77 deg K. The main radicals are accounted for in terms of C- H, OC-Cl, and C- COCl bond scissions and their relative abundance is significantly influenced by the chemical structure of the parent molecules. A mechanism is suggested. (auth)

• Research Organization: Univ., Pavia, Italy
• NSA Number: NSA-29-000161
• OSTI ID: 4425187
• Journal Information: J. Chem. Soc., B, no. 11, pp. 1563-1565, Journal Name: J. Chem. Soc., B, no. 11, pp. 1563-1565; ISSN JCSPA
• Country of Publication: United Kingdom
• Language: English

Related Subjects

*ACID HALIDES-- RADIOLYSIS
*ORGANIC CHLORINE COMPOUNDS-- RADIOLYSIS
ELECTRON SPIN RESONANCE
GAMMA RADIATION
LOW TEMPERATURE
N40300* --Chemistry--Radiation Chemistry
PHOTON BEAMS
POLYCRYSTALS
RADIATION CHEMISTRY
RADICALS
STRUCTURAL CHEMICAL ANALYSIS