ELECTRON-SPIN MAGNETIC RESONANCE OF FREE-RADICAL INTERMEDIATES IN GAMMA- IRRADIATED HYDROCARBONS
Technical Report
·
OSTI ID:4628629
ABS>Results of a study of the character and origin of the electron-spin magnetic-resonance spectra of gammairradiated hydrocarbon compounds are presented. The compounds examined include selected alkanes, alkenes, alkynes, branched alkames, and cycloparaffins. All irradiations and resonance measurements were performed at 77 deg K. Spectral analysis was directed toward identification of the chemical species responsible for the observed hyperfine patterns. Structural interpretation was confined to free-radical species resulting from carbon- hydrogen and carbon-carbon bond scission in the parent molecule. These results are incorporated into an evaluation of the current status of free-radical spectra from irradiated hydrocarbons. (auth)
- Research Organization:
- General Dynamics/Fort Worth. Div. of General Dynamics Corp., Fort Worth, Tex.
- NSA Number:
- NSA-17-039103
- OSTI ID:
- 4628629
- Report Number(s):
- NARF-63-4T; AD-417705; MR-N-29
- Country of Publication:
- United States
- Language:
- English
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