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Solid-state amperometric NO{sub x} sensor using sodium ion conductor

Conference ·
OSTI ID:441262

There has been a growing awareness of the need for in situ NO{sub x} (NO and NO{sub 2}) monitoring in combustion exhausts and environmental atmosphere. Several solid-electrolyte NO{sub x} sensors have so far been proposed and examined. These sensor devices, mostly of potentiometric type fabricated by using a couple of solid electrolyte/nitrate auxiliary phase (Type III). The authors have reported that a NASICON (sodium ion conductor)/nitrite couple shows excellent sensing characteristics, especially to NO{sub 2}. However, there has been little work on solid-state amperometric NO{sub x} sensors though it is known that amperometry, if properly fabricated, can give more precise concentration data in a limited concentration range than potentiometry. In this study, an attempt was made for an amperometric NO{sub x} sensor device using a NASICON/nitrite (or nitrate) couple.

OSTI ID:
441262
Report Number(s):
CONF-960782--
Country of Publication:
United States
Language:
English

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