Effect of anions on the rate of exchange of ligands and solvate displacement in tributyl phosphate solutions of uranyl ions (in Russian)
Journal Article
·
· Zh. Neorg. Khim., v. 18, no. 10, pp. 2807-2813
OSTI ID:4389216
From the temperature dependences of spin-spin nuclear magnetic relaxation times of /sup 31/P, the exchange rates of ligands, and solvate displacements, the thermodynamic parameters of activation for solutiong of uranyl chloride, bromide, nitrate, sulfate, and perchlorate in tributyl phosphate were determined. The exchange rate of ligands depended on the type of anion and increased in tbe sequence Cl, Br, NO/sub 2/, SO/sub 4/, ClO/sub 4/. The more labile complexes showed greater displacements. The effects of complex formation of the uranyl ion with tributyl phosphate are discussed. (tr-auth)
- Research Organization:
- Originating Research Org. not identified
- NSA Number:
- NSA-29-012626
- OSTI ID:
- 4389216
- Journal Information:
- Zh. Neorg. Khim., v. 18, no. 10, pp. 2807-2813, Journal Name: Zh. Neorg. Khim., v. 18, no. 10, pp. 2807-2813; ISSN ZNOKA
- Country of Publication:
- Country unknown/Code not available
- Language:
- Russian
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