THE HEATS OF FORMATION OF METAL HALIDES. ZIRCONIUM TETRACHLORIDE

Journal Article · Tue Oct 01 04:00:00 EDT 1957 · Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II

DOI:https://doi.org/10.1039/tf9575301285· OSTI ID:4333316

Gross, P; Hayman, C; Levi, D L

In order to determine the heat of formation of ZrCl/sub 4/, the heat evolved in the reaction Zr (s) + 2 Cl/sub 2/ (l) yields ZrCl/sub 4/(s) has been measured. The derived heat of formation of ZrCl/sub 4/ from Zr and liquid Cl is --225.89 kcal/mole, leading to a value of --234.7 kcal/mole for the standard heat of formation. The heat of interaction between Cl and ZrCl/sub 4/ was shown to be negligible. (auth)

• Research Organization: Fulmer Research Inst., Ltd., Stoke Poges, Buckinghamshire
• NSA Number: NSA-12-000079
• OSTI ID: 4333316
• Journal Information: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II, Journal Name: Transactions of the Faraday Society (England) Superseded by J. Chem. Soc., Faraday Trans., I and II Vol. Vol: 53; ISSN TFSOA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

CHEMISTRY
CHLORINE
HALIDES
INTERACTIONS
METALS
SPECIFIC HEAT
ZIRCONIUM
ZIRCONIUM CHLORIDES