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THERMOMETRIC (ENTHALPYMETRIC) TITRATION OF FREE ACID IN THE PRESENCE OF CERTAIN HYDROLYZABLE IONS

Technical Report ·
DOI:https://doi.org/10.2172/4329339· OSTI ID:4329339

The free acid is determined by titrating the sample solution with a standard base and recording the change in temperature. The plot of temperature vs. volume of titrant added is made automatically by a recording potentiometer. The end point of the titration is obtained by extrapolation of the straight-line portions of the curve. Systems studied were zirconium in hydrofluoric acid, uranyl ion in sulfuric acid and nitric acid, and thorium in nitric acid. (W.D.M.)

Research Organization:
Oak Ridge National Lab., Tenn.
DOE Contract Number:
W-7405-ENG-26
NSA Number:
NSA-12-012255
OSTI ID:
4329339
Report Number(s):
ORNL-2489
Country of Publication:
United States
Language:
English

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