Secondary deuterium isotope effects in the Baeyer-Villiger reaction
Journal Article
·
· Journal of the American Chemical Society
Observed isotope effects for the Baeyer- Villiger reaction of PhCD2 COCH3 (D2), PhCH2COCD (D3), and PhCD2COCD3 (D are reported. The isotope effect on the migrating group is smaller than expected; the general trend predicts a larger per deuterium isotope effect for RCH2 than for CH3.
- Research Organization:
- Univ. of Toronto
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-29-024019
- OSTI ID:
- 4312101
- Journal Information:
- Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 6 Vol. 96; ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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