A convenient, mild method for oxidative cleavage of alkenes with Jones reagent/osmium tetraoxide
Journal Article
·
· Journal of Organic Chemistry
- Pennsylvania State Univ., University Park, PA (United States)
Oxidative scission of alkenes is used for preparation of carboxylic acids and ketones. The authors present a method for cleavage of terminal olefins to yield a carboxylic acid based on the realization that a catalytic amount of osmium tetraoxide chromate should convert an olefin via a diol to an acid and/or ketone. The authors believe that and the osmium is then reoxidized by the chromate, which also cleaves the 1,2-diol. 1 tab.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 430924
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 17 Vol. 58; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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