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Performance of lithium/V{sub 2}O{sub 5} xerogel coin cells

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1837239· OSTI ID:428160
; ; ;  [1]
  1. Univ. of Minnesota, Minneapolis, MN (United States)

Vanadium pentoxide xerogel (XRG) materials have shown promise for use as cathodes in high energy density batteries. A composite cathode was formed from a mixture of the XRG, carbon, and two binders and studied in a coin cell configuration. The cathode, separator, and lithium anode were stacked in a 2,016 coil cell container, and a liquid electrolyte was used for the investigation. In contrast to thin film configurations where 4 Li{sup +} ions may be inserted per mole of the XRG host, the composite cathode supported the insertion of less than 2 Li{sup +} ions per mole of V{sub 2}O{sub 5} (XRG). It appears that morphology, electronic conductivity, and solid-state diffusivity combined to limit the performance of the cathodes.

Sponsoring Organization:
USDOE
OSTI ID:
428160
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 11 Vol. 143; ISSN 0013-4651; ISSN JESOAN
Country of Publication:
United States
Language:
English

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