RADIATION INDUCED REACTIONS BETWEEN IODINE AND ETHYL IODIDE
Technical Report
·
OSTI ID:4271941
A kinetic study was carried out on the radiationinduced reactions in a solution of iodine in ethyl iodide, using I/sup 131/ at for both the radiation soarce and tracer for some of the chemical reactions. Within a particular region of concentration and radiation intensity the rate of the reaction C/sub 2/H/sub 5/ I + I/sub 2/ b 2/ + Sn. Suff C/sub2/H/sub 5/I + I/sub 2/ fol lows the rate law dlx/dt = k(EtI)/sup 2/3/(I/sub 2/)sup 2/3/(Rad)/sub 2/3/. From a reaction m echanism in which hot ethyl radicals recoil from the track of the ionizing radiation and react with iodine molecules this same rate law can be derived. (auth)
- Research Organization:
- Pennsylvania State Univ., University Park. Coll. of Chemistry and Physics
- NSA Number:
- NSA-13-008758
- OSTI ID:
- 4271941
- Report Number(s):
- NYO-3984
- Country of Publication:
- United States
- Language:
- English
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