EFFECTS OF NUCLEAR TRANSFORMATIONS ON THE BROMATES. THE DECOMPOSITION OF THE BROMATE ION UNDER THE EFFECT OF AN ISOMERIC TRANSITION

Journal Article · Fri May 01 04:00:00 EDT 1959 · Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides

OSTI ID:4252852

Campbell, I G

The chemical effects of an isomeric transition on bromate ions in solution were studied. Some indications were found of the formation of an instable "bromites" fragment produced in aqueous solution and which can be reduced to a lower valence by methanol and eventually oxidized to the bromate state by oxidants. The neutralization of the charge of the 18-min. Br/sup 80/ to lower valences can not lead to the formation of bromate, and the formation of the stable bond Br -O during the discharge of the "bromite" fragment appears theoretically improbable. The "bromite" fragments are not hydrated at high pH. The effects of an isomeric transition on the bromate ion are comparable to the effects of the (n, gamma ) reactions on the oxy anions. (tr-auth)

• Research Organization: Institut de Recherches Nucleaires, Warsaw
• NSA Number: NSA-13-015160
• OSTI ID: 4252852
• Journal Information: Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides, Journal Name: Journal de Chimie Physique (France) Merged with Rev. Gen. Colloides to form J. Chim. Phys. Rev. Gen. Colloides Vol. Vol: 56; ISSN JCPQA
• Country of Publication: Country unknown/Code not available
• Language: French

Related Subjects

ACIDITY
ANIONS
ATOMIC MODELS
ATOMS
BINDING ENERGY
BROMATES
BROMIC ACID
BROMIDES
BROMINE 80
BROMINE COMPOUNDS
BROMINE OXIDES
CHEMICAL REACTIONS
CHEMICALS
CHEMISTRY
CONFIGURATION
DECOMPOSITION
ELECTRIC CHARGES
FREE RADICALS
GAMMA RADIATION
HALF-LIFE
IONS
ISOMERS
MEASURED VALUES
METHANOL
MOLECULES
NEUTRON BEAMS
NUCLEAR REACTIONS
OXIDATION
OXYGEN
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
REDUCTION
SOLUTIONS
STABILITY
TABLES
WATER