THE CRYSTAL STRUCTURE OF RUTHENOCENE
>Dicyclopentadienylruthenium, or ruthenocene, crystallizes in the orthorhombic space group Pnma with a = 7.13, b = 8.99, c = 12.81 A. There are four Ru(C/sub 5/H/sub 5/)/sub 2/ molecules per unit cell. The ruthenium atoms form approximately a face-centered lattice, and the cyclopentadienyl rings lie in an eclipsed configuration with respect to each other about each ruthenium atom. The structure was refined by Fourier and least-squares methods with 791 independent refiections. The ruthenium-carbon distance is 2.21 A, and the carboncarbon bond distance in the rings averages 1.43 A. (auth)
- Research Organization:
- Univ. of California, Berkeley
- NSA Number:
- NSA-13-007887
- OSTI ID:
- 4251589
- Journal Information:
- Acta Cryst., Journal Name: Acta Cryst. Vol. Vol: 12
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
THE CHEMISTRY OF NUCLEAR PROCESSES. II. APPLICATION OF URANIUM FISSION TO THE SYNTHESIS OF CARRIER-FREE RUTHENOCENE (Ru$sup 103$)
Homoannular disubstituted ruthenocenes containing a trifluoromethyl(tetramethyl)cyclopentadienyl ligand
Mechanistic organometallic photochemistry: observation of metastable ruthenocenium in photolysis of ruthenocene
Journal Article
·
Fri Mar 31 23:00:00 EST 1961
· Z. Naturforsch
·
OSTI ID:4052794
Homoannular disubstituted ruthenocenes containing a trifluoromethyl(tetramethyl)cyclopentadienyl ligand
Journal Article
·
Wed Feb 14 23:00:00 EST 2018
· Russian Chemical Bulletin
·
OSTI ID:22863391
Mechanistic organometallic photochemistry: observation of metastable ruthenocenium in photolysis of ruthenocene
Journal Article
·
Thu Jul 05 00:00:00 EDT 1984
· Inorg. Chem.; (United States)
·
OSTI ID:6611772