ZIRCONIUM COMPLEXES IN AQUEOUS SOLUTION. I. REACTION WITH MULTIDENTATE LIGANDS

Journal Article · Wed Jan 20 04:00:00 EST 1960 · Journal of the American Chemical Society (U.S.)

DOI:https://doi.org/10.1021/ja01487a027· OSTI ID:4197781

Intorre, B I; Martell, A E

A study of the interaction of Zr(IV) with a wide variety of chelating agents resulted in the discovery of a number of chelates with multidentate oxygen donor groups stable over a wide range of pH. The most stable chelate compounds were formed with disodium 1,2-dihydroxybenzene-3,5disulfonate, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, N- hydroxyethylethylenediaminetriacetic acid. N-hydroxyethyliminodiacetic acid, and N,N-dihydroxyethylglycine. Ethylenediaminetetraacetic acid was less effective, while trimethylenediaminetetraacetic acid does not lead to the formation of soluble complexes. (auth)

• Research Organization: Clark Univ., Worcester, Mass.
• Sponsoring Organization: USDOE
• NSA Number: NSA-14-007346
• OSTI ID: 4197781
• Journal Information: Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 82; ISSN JACSA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ACETIC ACID
ACIDITY
AMINO ACIDS
CHELATES
CHEMICAL REACTIONS
CHEMICALS
CHEMISTRY
DTPA
EDTA
ETHYL RADICALS
ETHYLENE
GLYCINE
HEDTA
HEIDA
HYDROXIDES
INTERACTIONS
ORGANIC NITROGEN COMPOUNDS
SOLUTIONS
STABILITY
SULFONIC ACIDS
WATER
ZIRCONIUM COMPLEXES