MECHANISM OF SUBSTITUTION REACTIONS OF COMPLEX IONS. XVI. EXCHANGE REACTIONS OF PLATINUM(II) COMPLEXES IN VARIOUS SOLVENTS
Journal Article
·
· Journal of the American Chemical Society (U.S.)
The rate of chloride exchange of trans-Py(py)/sub 2/Cl/sub 2/ in a variety of solvents depends upon the properties of the solvent in a way consistent with strong interaction of the solvent and metal ion in the rate- determining step. Solvents with empty, or potentially empty, orbitals are partictularly effective probably because of pi -bonding to the platinum. The term biphilic reagent is proposed for substances wbich can simultaneously donate and accept electrons in substitution reactions. (auth)
- Research Organization:
- Northwestern Univ., Evanston, Ill.
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-14-009393
- OSTI ID:
- 4195339
- Journal Information:
- Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 82; ISSN JACSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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