DETERMINATION OF DEUTERIUM IN WATER AND ORGANIC COMPOUNDS

Journal Article · Sun May 01 00:00:00 EDT 1960 · Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed.

DOI:https://doi.org/10.1021/ac60162a051· OSTI ID:4190872

Tamiya, N

Deuterium in water and organic compounds is usually determined by combustion to water, reduction to hydrogen by heated zinc, and mass spectrometric analysis. The method is modified in such a way that memory effects of the apparatus and isotope fractionation from partial reduction are avoided. The zinc reductant is replaced with a platinum-coated zinc reductant, and the reduction tube is completely redesigned. However, the combustion tube still has a memory effect and hence must be pretreated twice with the sample. (D.L.C.)

• Research Organization: Tokyo Medical and Dental Univ.
• Sponsoring Organization: USDOE
• NSA Number: NSA-14-013697
• OSTI ID: 4190872
• Journal Information: Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed., Journal Name: Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed. Vol. Vol: 32; ISSN ANCHA
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

CHEMISTRY
COATING
COMBUSTION
DEUTERIUM
HEATING
HYDROGEN
INSTRUMENTS
MASS SPECTROMETERS
ORGANIC COMPOUNDS
PLANNING
PLATINUM
QUANTITATIVE ANALYSIS
REDUCTION
TUBES
WATER
ZINC