SOME ASPECTS OF THE RADIATION CHEMISTRY OF LIQUID ALIPHATIC CARBOXYLIC ACIDS
Journal Article
·
· Journal of Physical Chemistry (U.S.)
The decomposition of ten aliphatic carboxylic acids by gamma -radiation was studied with particular reference to their relative rates of decarboxylation. The effects of structural variation, added iodine, and temperature were investigated as well as the distribution of free radicals for one of the acids as determined by radio-iodine trapping techniques. It is suggested that the mechanism of decarhoxylation involves the intermediate formation of free alkyl and carboxyl radicals. (auth)
- Research Organization:
- Florida State Univ., Tallahassee
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-14-005233
- OSTI ID:
- 4189786
- Journal Information:
- Journal of Physical Chemistry (U.S.), Journal Name: Journal of Physical Chemistry (U.S.) Vol. Vol: 63; ISSN JPCHA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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