STRUCTURE AND MAGNETIC PROPERTIES OF LiCuCl$sub 3$ /center dot/ 2H$sub 2$O
Journal Article
·
· Journal of Chemical Physics (U.S.)
X-ray and magnetic studies were carried out on LiCuC1/sub 3/ 2H/sub 2/0. The x-ray study, carried out on monoclinic crystals, gives lattice constants a = 6.078, b = 11.145, c = 9.145 A, beta = 108 50' and a space group = P2/sub 1/c. The strurture indicates that a ground state triplet is to be expected, and the paramagnetism of the crystals down to 5.9 deg K supports the existence of such a triplet, the reciprocal of molar susceptibility vs. T curve approximating that expected for the triplet rather than those for the singlet or independent ions. The susceptibility is not reversible above 220 deg K. (D.L.C.)
- Research Organization:
- Iowa State Univ. of Science and Tech., Ames
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-14-016652
- OSTI ID:
- 4181460
- Journal Information:
- Journal of Chemical Physics (U.S.), Journal Name: Journal of Chemical Physics (U.S.) Vol. Vol: 32; ISSN JCPSA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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