EQUILIBRIUM BETWEEN URANIUM METAL, URANIUM TRICHLORIDE, URANIUM TETRACHLORIDE IN THE FUSED SODIUM CHLORIDE-CALCIUM CHLORIDE BATH
Journal Article
·
· Denki Shikensho Iho (Japan) Changed to Denshi Gijutsu Sogo Kenkyusho Iho
OSTI ID:4178892
The equilibrium between uranium metal, uranium trichloride, and uranium tetrachloride dissolved in a molten melt containing 50 M% sodium and 50 M% calcium chloride was measured under carefully controlled experimental conditions. The trivalent uranium was determined to be 34 wt.% in the melt at 550 to 800 deg . The equilibrium constant for the reaction, 3 UCl/sub 4/ (NaCl-CaCl/sub 2/ melt) + U (solid) = 4UCl/sub 3/ (NaCl- CaCl/sub 2/ melt) was calculated, and the uranium concentration and the bath temperature were found to have no effect on the equilibrium in the range of the experiment. (auth)
- Research Organization:
- Originating Research Org. not identified
- NSA Number:
- NSA-14-021441
- OSTI ID:
- 4178892
- Journal Information:
- Denki Shikensho Iho (Japan) Changed to Denshi Gijutsu Sogo Kenkyusho Iho, Journal Name: Denki Shikensho Iho (Japan) Changed to Denshi Gijutsu Sogo Kenkyusho Iho Vol. Vol: 22; ISSN DESIA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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