SOME METAL COMPLEXES OF CITRIC AND TRICARBALLYLIC ACIDS

Journal Article · Mon Nov 30 23:00:00 EST 1959 · J. Inorg. & Nuclear Chem.

DOI:https://doi.org/10.1016/0022-1902(59)80101-9· OSTI ID:4175128

Li, N C; Lindenbaum, A; White, J M

The formation constants of several metal complexes of citrate and tricarballylate, and of the "hydrogen complexes," i.e., complexes in which HA/sup 2/- act as ligands, were determined by a titrimetric method. For Mn(II), Cd(II), Zn(II), and Ni(II) complexes of citrate, the value of K/sub MA//K/sub MHA/ varies from 10/sup 1.6/ to 10/sup 1.9/, the ratio increasin g with increasing value of K/ sub MA/. The citrate complexes are more stable than the corresponding tricarballylate complex, as expected. The Co(II) and Mg complexes of citrate have reduction potentials which are too negative for direct polarographic method. In the pH region 1.9 to 2.5 the 1: 1 uranyl-citrate complex has been shown to be a monomer with log K/sub MA/ = 8.5. (auth)

• Research Organization: Argonne National Lab., Lemont, Ill.; Duquesne Univ., Lemont, Ill.
• NSA Number: NSA-14-009417
• OSTI ID: 4175128
• Journal Information: J. Inorg. & Nuclear Chem., Journal Name: J. Inorg. & Nuclear Chem. Vol. Vol: 12
• Country of Publication: Country unknown/Code not available
• Language: English

Related Subjects

ACIDITY
CADMIUM COMPLEXES
CHEMISTRY
CITRIC ACID
COBALT COMPLEXES
COMPLEXES
ELECTRIC POTENTIAL
MAGNESIUM COMPLEXES
MANGANESE COMPLEXES
METALS
NICKEL COMPLEXES
ORGANIC ACIDS
POLAROGRAPHY
PROPANE
QUALITATIVE ANALYSIS
QUANTITATIVE ANALYSIS
REDUCTION
STABILITY
TRICARBALLYLIC ACID
URANYL COMPOUNDS
ZINC COMPLEXES