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U.S. Department of Energy
Office of Scientific and Technical Information

PHYSICAL METALLURGY OF TUNGSTEN AND TUNGSTEN BASE ALLOYS. Period covered: April 1, 1958 to November 30, 1959

Technical Report ·
OSTI ID:4163040
Base line data revealed that the tensile transition temperature of W is not strongly influenced by gaseous impurities of 10 to 50 ppm but may be affected by metallic impurities of 10 to 30 ppm. The recrystallization temperature of W (1300 to 1400 deg C for 30 anneals) was increased to approximately 1800 deg C by the presence of 50 ppm of Al. Trace impurity levels exhibited only slight influence on tensile behavior of W up to 2700 deg C, but at 2250 to 2700 deg C ductility decreased sharply with increasing temperature and was accompanied by an anomalous and poorly reproducible creep-rupture bebavior. Deformation of single crystals is accompanied by twinning. Low-temperature yield point phenomena were observed and are tentatively attributed to H. Polycrystalline W exhibited several low magnitude internal friction peaks of undetermined origin at 65, 150, 550, and 700 deg C. Single crystals after a 400 deg C anneal showed no peaks. Purposeful introduction of C and O into W at elevated temperatures did not produce homogeneous distributions of these elements in concentrations above 20 to 40 ppm. The addition of ThO/sub 2/ in concentrations of 2 to 4 wt.% increased the recrystallization temperature of W by 400 to 600 deg C and thereby increased the yield strength at 2700 deg F by a factor of 2 to 3.5 (to 33,000 psi) and the 100- hr creep rupture strength by a factor of 2. The addition of 0.38 wt.% TaC as a dispersed second phase in W increased the yield stress at 2500 deg F to 56,000 psi. (C.J.G.)
Research Organization:
Westinghouse Electric Corp. Lamp Div., Bloomfield, N.J.
NSA Number:
NSA-14-023306
OSTI ID:
4163040
Report Number(s):
WADD-TR-60-37
Country of Publication:
United States
Language:
English