GAMMA RADIATION EFFECTS ON FORMATION AND REACTIONS OF FREE RADICALS IN SOLID AMMONIA AND HYDRAZINE

Journal Article · Thu Aug 01 04:00:00 EDT 1963 · Zhurnal Fizicheskoi Khimii (U.S.S.R.) For English translation see Russ. J. Phys. Chem. (Engl. Transl.)

OSTI ID:4154152

Tupikov, V I; Pshezhetskii, S Ya

Reactions of NH/sub 2/ radicals with NH/sub 3/ molecules and recombination of NH/sub 2/ radicals as a result of gamma irradiation of solid ammonia were studied using the method of electron paramagnetic resonance. The data indicated that the radical recombinations induced by gamma rays are the result of migration of free valence electrons and hydrogen atoms. The mechanism results in a maximum radical concentration. Effects of ultraviolet rays on recombination of NH/sub 2/ and N/sub 2/H/sub 3/ radicals in solid ammonium and hydrazine were investigated. It was found that ultraviolet-induced reaction between OH radical and NH/sup 3/ at liquid hydrogen temperature formed NH/sup 2/ and HO/sup 2/ radicals. (R.V.J.)

• Research Organization: Karpov Research Inst. of Physics and Chemistry
• NSA Number: NSA-18-001774
• OSTI ID: 4154152
• Journal Information: Zhurnal Fizicheskoi Khimii (U.S.S.R.) For English translation see Russ. J. Phys. Chem. (Engl. Transl.), Journal Name: Zhurnal Fizicheskoi Khimii (U.S.S.R.) For English translation see Russ. J. Phys. Chem. (Engl. Transl.) Vol. Vol: 37; ISSN ZFKHA
• Country of Publication: Country unknown/Code not available
• Language: Russian

Related Subjects

AIR
AMMONIA
CERAMICS
CHEMICAL REACTIONS
CHEMISTRY
COATING
COMBUSTION
ELECTRONS
FREE RADICALS
GAMMA RADIATION
GASES
HEATING
HIGH TEMPERATURE
HYDRAZINE
ION RECOMBINATION
JETS
MAGNETIC RESONANCE
MOLYBDENUM
OXIDATION
OXYGEN
RADIATION EFFECTS
REACTION KINETICS
SOLIDS
TABLES
TEMPERATURE
TESTING
THERMAL STRESSES
ULTRAVIOLET RADIATION