Synthesis and structural characterization of a tetranuclear organolanthanide hydrazido complex
- Univ. of New Orleans, LA (United States)
The authors describe the synthesis of a samarium cyclopentadienyl hydrazido complex. Cp*{sub 2}Sm (Cp* = {eta}{sup 5}-C{sub 5}Me{sub 5}) reacts with hydrazine giving the yellow crystalline product. Single-crystal diffraction was used to characterize the product. The molecule consists of distorted-tetrahedrons of samarium atoms bridged by hydrazido. 21 refs., 1 fig., 1 tab.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 415023
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 3 Vol. 11; ISSN 0276-7333; ISSN ORGND7
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and reactions of monomeric hydrazine and hydrazido complexes that contain the Cp*MoMe[sub 3] core
Diamagnetic (Pentamethylcyclopentadienyl)tungsten complexes containing unsubstituted, monomethyl, or 1,1-dimethyl hyrazine or hydrazido ligands
Synthesis, structure, and reactivity of the iridium hydrazido-bridged complex Cp*Ir({mu}-C{sub 6}H{sub 4}N-NC{sub 6}H{sub 4})IrCp
Journal Article
·
Tue Jun 08 20:00:00 EDT 1993
· Inorganic Chemistry; (United States)
·
OSTI ID:6000457
Diamagnetic (Pentamethylcyclopentadienyl)tungsten complexes containing unsubstituted, monomethyl, or 1,1-dimethyl hyrazine or hydrazido ligands
Journal Article
·
Tue Oct 06 20:00:00 EDT 1992
· Journal of the American Chemical Society
·
OSTI ID:457064
Synthesis, structure, and reactivity of the iridium hydrazido-bridged complex Cp*Ir({mu}-C{sub 6}H{sub 4}N-NC{sub 6}H{sub 4})IrCp
Journal Article
·
Tue Aug 01 00:00:00 EDT 1995
· Organometallics
·
OSTI ID:102858