Niobium (IV) compounds containing ethoxide. [NbCl(OC2H5)3(C5H5N)]2 and Nb(OC2H5)4
Journal Article
·
· Inorganic Chemistry (U.S.)
Investigations of niobium(IV) solutions in ethyl alcohol led to the preparation of two diamagnetic compounds, d Nb(OC2H5)4. The former is prepared by the addition of pyridine to niobium(IV) chloride solutions in ethyl alcohol. The structure of the dimer is thought to involve chloride bridging on the basis of its chemical properties. Nb(OC2H5)4 is prepared by the reaction of NaOC2H5 with STANbCl(OC2H5 )3(C5H5)2. Both compounds are readily converted to (C5H6N)2STANb(OC2H5) Cl5.
- Research Organization:
- Michigan State Univ., East Lansing
- Sponsoring Organization:
- USDOE
- NSA Number:
- NSA-18-006840
- OSTI ID:
- 4144531
- Journal Information:
- Inorganic Chemistry (U.S.), Journal Name: Inorganic Chemistry (U.S.) Vol. Vol: 3; ISSN INOCA
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
Similar Records
Synthesis and characterization of gallium and indium thiolate complexes. Crystal and molecular structures of [M(SC{sub 5}H{sub 4}N){sub 3}] (M = Ga, In), [In(SC{sub 5}H{sub 3}N-3-SiMe{sub 3}){sub 3}], and [M{sub 2}(OC{sub 2}H{sub 4}){sub 2}(SC{sub 5}H{sub 4}N){sub 4}] (M = Ga, In)
PREPARATION OF NIOBIUM BY REDUCTION OF NbCl$sub 5$ BY HYDROGEN
Synthesis of two mercaptide-substituted hexanuclear molybdenum halide clusters. [((Mo/sub 6/Cl/sub 8/)(SCH/sub 2/CH/sub 3/)/sub 4/(C/sub 5/H/sub 5/N)/sub 2/) and Na/sub 2/((Mo/sub 6/Cl/sub 8/)(SCH/sub 2/CH/sub 3/)/sub 6/) x 3(C/sub 5/H/sub 5/N)]
Journal Article
·
Wed Jul 19 00:00:00 EDT 1995
· Inorganic Chemistry
·
OSTI ID:483604
PREPARATION OF NIOBIUM BY REDUCTION OF NbCl$sub 5$ BY HYDROGEN
Journal Article
·
Sat Feb 29 23:00:00 EST 1964
· Zh. Prikl. Khim.
·
OSTI ID:4019709
Synthesis of two mercaptide-substituted hexanuclear molybdenum halide clusters. [((Mo/sub 6/Cl/sub 8/)(SCH/sub 2/CH/sub 3/)/sub 4/(C/sub 5/H/sub 5/N)/sub 2/) and Na/sub 2/((Mo/sub 6/Cl/sub 8/)(SCH/sub 2/CH/sub 3/)/sub 6/) x 3(C/sub 5/H/sub 5/N)]
Technical Report
·
Mon Feb 28 23:00:00 EST 1977
·
OSTI ID:7313701