Synthesis and regeneration of lead (IV) acetate
- Sandia National Labs., Albuquerque, NM (United States). Advanced Materials Lab.
Lead acetate [Pb(O{sub 2}CMe){sub 4}] was easily synthesized from a warm solution of Pb{sub 3}O{sub 4}, HO{sub 2}CMe and O(OCMe){sub 2} following literature preparations when the appropriate measures to minimize water contamination were followed. Furthermore, Pb(O{sub 2}CMe){sub 4} which has been decomposed (evidenced by the appearance of a purple color due to oxidation) can be regenerated using a similar preparatory route. Introduction of Pb(O{sub 2}CMe){sub 4} from the two routes outlined above into the IMO process for production of PZT thin films gave films with comparable ferroelectric properties to commercially available Pb(O{sub 2}CMe){sub 4} precursors. However, the freshly synthesized material yields PZT films with better properties compared to the recycled material.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE Office of Energy Research, Washington, DC (United States)
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 414331
- Report Number(s):
- SAND--96-2635; ON: DE97001472
- Country of Publication:
- United States
- Language:
- English
Similar Records
Controlled stoichiometric incorporation of Ti(IV) into a Zr(IV) pinacolate
Study of x CNFO + (1-x) PLZT magnetoelectric composites
Pyroelectric response of lead zirconate titanate thin films on silicon: Effect of thermal stresses
Journal Article
·
Sun Nov 01 23:00:00 EST 1998
· Inorganic Chemistry
·
OSTI ID:316209
Study of x CNFO + (1-x) PLZT magnetoelectric composites
Journal Article
·
Thu Apr 24 00:00:00 EDT 2014
· AIP Conference Proceedings
·
OSTI ID:22269423
Pyroelectric response of lead zirconate titanate thin films on silicon: Effect of thermal stresses
Journal Article
·
Wed Nov 27 23:00:00 EST 2013
· Journal of Applied Physics
·
OSTI ID:22258733