Controlled stoichiometric incorporation of Ti(IV) into a Zr(IV) pinacolate
- Indiana Univ., Bloomington, IN (United States)
The first Ti/Zr mixed-metal alkoxide was synthesized by the reaction of equimolar amounts of Ti(O{sup i}Pr){sub 4} and Zr{sub 2}(OCMe{sub 2}CMe{sub 2}O){sub 2}(OCMe{sub 2}CMe{sub 2}OH){sub 4} to give TiZr{sub 2}(OCMe{sub 2}CMe{sub 2}O){sub 4}(OCMe{sub 2}CMe{sub 2}OH){sub 2}(O{sup i}Pr){sub 2}. The 1:1 (Ti:Zr) mixed-metal product was obtained by reaction of Ti(O{sup i}Pr){sub 4} and Zr{sub 2}(OCMe{sub 2}CMe{sub 2}O){sub 2}(OCMe{sub 2}CMe{sub 2}OH){sub 4} (2:1 mole ratio, respectively) yielding Ti{sub 2}Zr{sub 2}(OCMe{sub 2}CMe{sub 2}O){sub 6}(O{sup i}Pr){sub 4}. Both products were characterized by X-ray diffraction. Crystallographic data are given.
- OSTI ID:
- 316209
- Journal Information:
- Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 22 Vol. 37; ISSN 0020-1669; ISSN INOCAJ
- Country of Publication:
- United States
- Language:
- English
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