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CARBON-CARBON BOND RUPTURE REACTIONS IN THE RADIOLYSIS OF 2,2,4-TRIMETHYL- PENTANE

Journal Article · · Journal of Physical Chemistry (U.S.)
DOI:https://doi.org/10.1021/j100806a523· OSTI ID:4137271
Initial G-values of H/sub 2/ and C/sub 1/--C/sub 7/ products form the radiolysis of 2,2,4-trimethylpentane (2,2,4-TMP) were measured. Scavenged and molecular yields of hydrogen, methane, propylene, isobutane, isobutene, heptanes, and heptenes were also obtained by adding iodine up to the saturated concentration. It was concluded that within the range of the products analyzed there should be four types of dissociation reactions in the radiolysis of 2,2,4- TMP. These reactions are discussed. (P.C.H.)
Research Organization:
Tokyo Inst. of Tech.
Sponsoring Organization:
USDOE
NSA Number:
NSA-18-005386
OSTI ID:
4137271
Journal Information:
Journal of Physical Chemistry (U.S.), Journal Name: Journal of Physical Chemistry (U.S.) Vol. Vol: 67; ISSN JPCHA
Country of Publication:
Country unknown/Code not available
Language:
English

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