THE KINETICS OF F$sub 3$B: N(CH$sub 3$$)$$sub 3$ HYDROLYSIS (in Russian)
Journal Article
·
· Zhur. Neorg. Khim.
OSTI ID:4136110
The synthesis and analysis of pure F/sub 3/B: N(CH/sub 3/)/sub 3/ are described. The hydrolysis of F/sub 3/B: N(CH/sub 3/)/sub 3/ is a first order reaction which does not accelerate in alkaline medium and is not catalyzed by H/ sup +/ ions. The hydrolysis rate (in min/sup -1/) constant as a function of temperature is expressed by lg (0.4343 k) = 14.52 - 5915T; the energy and hydrolysis activation entropy is 27.1 kcal/mol and 0.6 entropy units. The hydrolysis rate is inhibited by high salt concentrations. (R.V.J.)
- Research Organization:
- Dnepropetrovsk Inst. of Transportation, USSR
- NSA Number:
- NSA-14-025408
- OSTI ID:
- 4136110
- Journal Information:
- Zhur. Neorg. Khim., Journal Name: Zhur. Neorg. Khim. Vol. Vol: 5
- Country of Publication:
- Country unknown/Code not available
- Language:
- Russian
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