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Plutonium and americium in Lake Michigan sediments

Conference ·
OSTI ID:4130003

The vertical distributions of $sup 239$$,$$sup 240$Pu, $sup 238$Pu, and $sup 137$Cs have been measured in sediment cores taken from Lake Michigan. Sections from a limited number of cores have been analyzed for $sup 241$Am. In addition, grab samples from ten locations in the southern basin of the lake have been analyzed for phase distribution of $sup 239$$,$$sup 240$Pu using a sequential extraction technique. The results indicate that the $sup 239$$,$$sup 240$Pu, $sup 238$Pu, and $sup 137$Cs from weapons testing, and the $sup 241$Am formed in situ are concentrated in the sediments. A comparison of the total deposition of $sup 239$$,$$sup 240$Pu and $sup 137$Cs indicates that $sup 137$Cs may be valuable as a monitor for $sup 239$$,$$sup 240$Pu deposition in the sediments. Values of the $sup 238$Pu/$sup 239$$,$$sup 240$Pu ratio are in agreement with values reported in Lake Ontario sediments (and Lake Michigan plankton) and show little variation with depth. $sup 241$Am data support the concept of in situ production with little preferential mobility after formation. Studies of sedimentary phase distributions show that $sup 239$$,$$sup 240$Pu is associated with hydrous oxide phases which are chemically stable under the prevailing conditions in lake sediments. Since Lake Michigan sediments remain aerobic, relatively little $sup 239$$,$$sup 240$Pu is available for chemical mobilization from the hydrous oxide or organic phases present in the sediments. (auth)

Research Organization:
Argonne National Lab., Ill. (USA)
DOE Contract Number:
W-31109-ENG-38
NSA Number:
NSA-33-009258
OSTI ID:
4130003
Report Number(s):
CONF-751105--9; SM--199/47
Country of Publication:
United States
Language:
English