Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

THE RADIATION-INDUCED CHLORINATION OF TOLUENE BY STANNIC CHLORIDE

Journal Article · · Journal of Physical Chemistry (U.S.)
DOI:https://doi.org/10.1021/j100785a502· OSTI ID:4077054

Results of the radioinduced chlorination of toluene by stannic chloride are presented. It appears that combined m- and p-chlorotoluene yields are about 30% higher than the o-chlorotoluene yield, and that yields approach an asymptotic level. This level appears to be near G(C/sub 7/H/sub 7/Cl) = 0.2. There appears to be no dependence of chlorotoluene yields on dose, temperature, or ethylene concentration. However, there may be a direct dependence of yield on dose rate. (P.C.H.)

Research Organization:
Stanford Research Inst., Menlo Park, Calif.
Sponsoring Organization:
USDOE
NSA Number:
NSA-18-016094
OSTI ID:
4077054
Journal Information:
Journal of Physical Chemistry (U.S.), Journal Name: Journal of Physical Chemistry (U.S.) Vol. Vol: 68; ISSN JPCHA
Country of Publication:
Country unknown/Code not available
Language:
English

Similar Records

THE ROLE OF IONS IN THE RADIOLYSIS OF ORGANIC LIQUIDS
Technical Report · Thu Oct 31 23:00:00 EST 1963 · OSTI ID:4159490

The Radiation-Induced Oxidation of Stannous Chloride in Aqueous Hydrochloric Acid
Journal Article · Sun Dec 31 23:00:00 EST 1961 · Bulletin of the Chemical Society of Japan · OSTI ID:4763097

THE RADIATION-INDUCED OXIDATION OF STANNOUS CHLORIDE IN AQUEOUS HYDROCHLORIC ACID
Journal Article · Sat Dec 31 23:00:00 EST 1960 · Ann. Rept. Radiation Center Osaka Prefect. · OSTI ID:4829004