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Electronic Conduction in Single Crystals of Uranium Dioxide

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.1713588· OSTI ID:4071787
Electrical conductivity measurements between 90 and 800 deg K were performed on single crystals of uranium dioxide with compositions in the range UO/ sub 2.000/ to UO/sub 2.007/. The activation energy calculated from the ln sigma T vs 1/T curves decreases from 0.34 to 0.19 ev with increasing excess oxygen content. Hall effect measurements by d-c and a-c techniques yielded no measurable response, and indicate that the Hall mobility is smaller than 0.015 cm/ sup 2/v/sup -1/ sec/sup -1/ at room temperature. This result and a consideration of the fundamental parameters determining the transport mechanism suggest an interpretation based on small polaron theory.
Research Organization:
Centre d'Etude l'Energie Nucleaire, Mol, Belg.
Sponsoring Organization:
USDOE
NSA Number:
NSA-18-014495
OSTI ID:
4071787
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 4 Vol. 35; ISSN JAPIAU; ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
Country unknown/Code not available
Language:
English