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AN INFRARED AND ISOPIESTIC INVESTIGATION OF THE INTERACTION BETWEEN TRI-n- BUTYL PHOSPHATE AND MONO-(2-ETHYLHEXYL)-PHOSPHORIC ACID

Journal Article · · Journal of Physical Chemistry (U.S.)
DOI:https://doi.org/10.1021/j100821a036· OSTI ID:4062587
The interaction between tri-n-butyl phosphate and mono(2-ethylhexyl)- phosphonic acid was investigated. The method of continuous variations utilizing changes in infra red absorption and changes in the freezing point depression of the mixtures was used. Isopiestic measurements also were made. Results gave evidence that an association product had resulted at a ratio of 2 moles of TBP per hexamer unit of H/sub 2/MEHP. (auth)
Research Organization:
Argonne National Lab., Ill.
Sponsoring Organization:
USDOE
NSA Number:
NSA-15-012825
OSTI ID:
4062587
Journal Information:
Journal of Physical Chemistry (U.S.), Journal Name: Journal of Physical Chemistry (U.S.) Vol. Vol: 65; ISSN JPCHA
Country of Publication:
Country unknown/Code not available
Language:
English