SYNTHESIS OF INORGANIC POLYMER HIGH-TEMPERATURE FLUIDS. Progress Report No. 4, March 1961-May 1961
Investigation of phosphonitrilic chloride polymers stabilized against high-temperature polymerization by bonding to various metal halides was continued. Examples of metal halides which react with PCl/sub 5/ and NH/sub 4/Cl to give thermally stable (PNCl/sub 2/)/metal halide liquids were extended to include SnCl/ sub 4/, FeCl/sub 3/, CuCl. and TlCl. MgCl/sub 2/, CdCl/sub 2/, PbCl/sub 2/, and AgCl failed to give stabilized products. Preparations of (PNCl/sub 2/)/sub n// AlCl/sub 3/, (PNCl/sub 2n//SbCl/sub 3/, and (PNCl/sub 2/)/sub n//Z nCl/sub 2/ were further investigated. A new (PNCl/sub 2/)/sub n//SbCl/sub 3/ compound was obtained. and several (PNCl/sub 2/)/sub n//ZnCl/sub 2/ liquids of varying viscosity were prepared. Two new aryloxy phosphonitriles were prepared. Neither had satisfactory fluid characteristics, but they may serve as intermediates to more desirable fluids. (auth)
- Research Organization:
- Du Pont de Nemours (E.I.)& Co. Eastern Lab., Gibbstown, N.J.
- NSA Number:
- NSA-15-023370
- OSTI ID:
- 4058150
- Report Number(s):
- NP-10307; ELab-b-2-31
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
AMMONIUM COMPOUNDS
ANTIMONY CHLORIDES
AROMATICS
ARYL RADICALS
BONDING
CADMIUM CHLORIDES
CHEMISTRY
CHLORIDES
COPPER CHLORIDES
FLUIDS
HALIDES
HIGH TEMPERATURE
IRON CHLORIDES
LIQUIDS
MAGNESIUM CHLORIDES
METALS
NITROGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS CHLORIDES
PHOSPHORUS COMPOUNDS
POLYMERS
PREPARATION
STABILITY
THALLIUM CHLORIDES
TIN CHLORIDES
VISCOSITY
ZINC CHLORIDES