THE OXIDATION OF U(IV) BY Tl(III) OVER AN EXTENDED CONCENTRATION RANGE IN AQUEOUS-PERCHLORIC ACID SOLUTIONS
Technical Report
·
OSTI ID:4055893
The kinetics of the oxidation of U(IV) by Tl(III) were examined in aqueous-perchloric acid solution with the concentrations of U(IV) and Tl(III) varied over a 2000-fold range. The orders with respect to U(IV) and Tl(IlI) were found to be different in different concentration ranges. The data were explained using combinntions of four paths involving hydrolytic species. The temperature was varied from 15 to 50 deg C and the activation energy was found for each rate constant. (auth)
- Research Organization:
- Sandia Corp., Albuquerque, N. Mex.
- DOE Contract Number:
- AT(29-1)-789
- NSA Number:
- NSA-18-017779
- OSTI ID:
- 4055893
- Report Number(s):
- SC-4972(RR)
- Country of Publication:
- United States
- Language:
- English
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