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GAS CHROMATOGRAPHIC ANALYSIS OF SOME VOLATILE PHOSPHORUS COMPOUNDS

Journal Article · · Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed.
DOI:https://doi.org/10.1021/ac60172a013· OSTI ID:4053514
A rapid gas chromatographic method of analysis for mixtures of phosphorus trichloride-thiophosphoryl chloride, phosphorus trichloride - phosphoryl chloride, and dionethyl phosphite -diethyl phosphite was developed. The area per cent of each peak of the chromatogram closely agreed with the weight per cent of the corresponding component of the mixture. The column and detector used with the reactive inorganic compounds were constructed from inert materials. Described is a simple, yet dependable, thermal conductivity cell made from borosilicate glass with tantalum filaments. (auth)
Research Organization:
Kansas State Univ., Manhattan
Sponsoring Organization:
USDOE
NSA Number:
NSA-15-014213
OSTI ID:
4053514
Journal Information:
Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed., Journal Name: Analytical Chemistry (U.S.) Formerly Ind. Eng. Chem., Anal. Ed. Vol. Vol: 33; ISSN ANCHA
Country of Publication:
Country unknown/Code not available
Language:
English