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THE REACTION BETWEEN 2,2-DIPHENYL-1-PICRYLHYDRAZYL AND NITROGEN DIOXIDE

Journal Article · · Journal of Physical Chemistry (U.S.)
DOI:https://doi.org/10.1021/j100823a002· OSTI ID:4053278
; ;
The products of the reaction between nitrogen dioxide and 2,2-diphenyl-1- picrylhydrazyl are identified as being, contrary to previous ideas, mono- and dinitrated diphenylpicrylhydrazines. The hydrazyl free radicals corresponding to these hydrazines are prepared. The high-resolution proton nmr spectra of diphenylpicrylhydrazine and its nitro derivatives, and the paramagnetic resonance spectra of the corresponding hydrazyls, are described. (auth)
Research Organization:
Argonne National Lab., Ill.
Sponsoring Organization:
USDOE
NSA Number:
NSA-15-020711
OSTI ID:
4053278
Journal Information:
Journal of Physical Chemistry (U.S.), Journal Name: Journal of Physical Chemistry (U.S.) Vol. Vol: 65; ISSN JPCHA
Country of Publication:
Country unknown/Code not available
Language:
English

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Related Subjects

CHEMISTRY
ORGANIC NITROGEN COMPOUNDS
PHENYL RADICALS
PICRYL RADICALS