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COMBINATIONS FORMED BY THE SULFIDES OF THE ELEMENTS OF THE RARE EARTH GROUP. II. THE EQUILIBRIUM DIAGRAM OF THE SYSTEM YTTRIUM SULFIDE-CALCIUM SULFIDE (in French)

Journal Article · · Bull. soc. chim. France
OSTI ID:4032051
Phase diagrams were studied crystallographically on tempered products. Two regions of homogeneity were characterized. The first, a cubic phase of the Th/sub 3/P/sub 4/ type, is stable oniy at ligh temperature and has a eutectoid point at t = 980 deg C for the composition Y/sub 2/S/sub 3/-0.47 CaS. The second phase is cubic of the NaCl type near the calcium sulfide. Two varisties correspond to the formuia CaY/sub 2/S/sub 3/, one of which is orthorhombic of the Yb/sub 3/S/sub 4/ type and is stable up to 1110 deg C. The fusion curwe was constructed for the compositions richer in Y/sub 2/S/sub 3/. (tr-auth)
Research Organization:
Faculte de Pharmacie, Paris
NSA Number:
NSA-15-015596
OSTI ID:
4032051
Journal Information:
Bull. soc. chim. France, Journal Name: Bull. soc. chim. France Vol. Vol: No. 1
Country of Publication:
Country unknown/Code not available
Language:
French

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