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URANYL BROMIDES OBTAINED FROM AQUEOUS SOLUTION

Journal Article · · J. Inorg. & Nuclear Chem.
Uranyl bromide can be crystallized from acid solution as the very hygroscopic trinydrate. Part of the water can be removed at 60 deg C without decomposition, but irreversible decomposition takes place at 115 deg C. Its saturated solution is 6.5 M, viscous, very dark red, and of density 3.36 g/ml. Recrystallization from ether or isopropanol yields organic solvate-hydrates. The basic bromide, UO/sub 2/(OH)Br 2H/sub 2/O was crystallized from acid-deficient uranyl bromide solutions. It forms stable dilute aqueous solutions, but its concentrated solutions deposit hydrated uranium trioxide. (auth)
Research Organization:
Oak Ridge National Lab., Tenn.
NSA Number:
NSA-15-016943
OSTI ID:
4025159
Journal Information:
J. Inorg. & Nuclear Chem., Journal Name: J. Inorg. & Nuclear Chem. Vol. Vol: 17
Country of Publication:
Country unknown/Code not available
Language:
English

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