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Unique Dynamic Appearance of a Ge-Si Ad-dimer on Si(001)

Journal Article · · Physical Review Letters
We carry out a comparative study of the energetics and dynamics of Si-Si, Ge-Ge, and Ge-Si ad-dimers on top of a dimer row in the Si(001) surface, using first-principles calculations. The dynamic appearance of a Ge-Si dimer is distinctively different from that of a Si-Si or Ge-Ge dimer, providing a unique way for its identification by scanning tunneling microscopy (STM). Its ''rocking'' motion, observed in STM, actually reflects a 180{sup o} rotation of the dimer, involving a piecewise-rotation mechanism. The calculated energy barrier of 0.74eV is in good agreement with the experimental value of 0.82eV.
Sponsoring Organization:
(US)
OSTI ID:
40205940
Journal Information:
Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 26 Vol. 85; ISSN 0031-9007
Publisher:
The American Physical Society
Country of Publication:
United States
Language:
English

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