CHELATION AND OLATION REACTIONS OF AQUEOUS METAL IONS. Annual Progress Report for December 1, 1959-November 30, 1960
Technical Report
·
OSTI ID:4020016
Work on the chelation and olation reactions of aqueous metal ions is described. Quantitative data concerning the intersction of uranyl ions with a number of orgsnic ligands are presented. Equilibrium constants and thermodynamic data pertaining to the polymerization reactions of Fe(III) chelates were determined as an aid in understanding the nature of reactivities and stabilities of iron complexes. As a preliminary step in a thermodynamic study of the chelation and polymerization reactions of alkaline earth and rare earth ions, an investigation was made of the thermodynamics of alkaline earth chelate reactions. The results of non-equi-librium ultracentrifugation of mixed chelates of Zr(IV) and Th(IV) ions in which the total number of potential donor atoms of the ligands exactly matches the coordination number of the metal ion are described. Preliminary solvent extraction studies were made on the interaction of Th(IV) with N-hydroxyethylethylenediaminetriacetic acid. (auth)
- Research Organization:
- Clark Univ., Worcester, Mass.
- NSA Number:
- NSA-15-016875
- OSTI ID:
- 4020016
- Report Number(s):
- TID-11255
- Country of Publication:
- United States
- Language:
- English
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