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U.S. Department of Energy
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TETRAFLUOROHALATES OF CESIUM, RUBIDIUM AND POTASSIUM

Journal Article · · Journal of the American Chemical Society (U.S.)
DOI:https://doi.org/10.1021/ja01474a040· OSTI ID:4009502

Fluorination of alkali chlorides produces alkali tetrafluorochlorates, MClF/sub 4/, and is explained by the reaction MCl + 2 F/sub 2/ = MClF/sub 4/. Cesium and potassium tetrafluorochlorates were prepared at 90--250 deg . The order of stability is Cs) Rb) K, and the order of reactivity with water is Cl) Br)I. (P.C.H.)

Research Organization:
Los Alamos Scientific Lab., N. Mex.
Sponsoring Organization:
USDOE
NSA Number:
NSA-15-025950
OSTI ID:
4009502
Journal Information:
Journal of the American Chemical Society (U.S.), Journal Name: Journal of the American Chemical Society (U.S.) Vol. Vol: 83; ISSN JACSA
Country of Publication:
Country unknown/Code not available
Language:
English

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