REACTIONS OF HYDROGEN FLUORIDE WITH METALS AND METALLOIDS
Journal Article
·
· J. Inorg. & Nuclear Chem.
Closed-system reactions of liquid hydrogen fluoride with a number of metals, metalloids, and refractory materials were investigated. The reaction with metals proved to be a good route to pure fluorides. The closed system furnished two unique features: (1) the hydrogen generated in the fluorination maintained a strong reducing atmosphere that permitted isolation of otherwise difficultly obtainable fluorides of lower oxidation state, e.g., TiF/sub 3/ and NbF/sub 3/ and (2) the hydrogen is also believed to have contributed significantly to the reactivity of many of the transition metals by forming a metal hydride intermediate. (auth)
- Research Organization:
- E.I. Du Pont de Nemours & Co., Wilmington, Del.
- NSA Number:
- NSA-15-026033
- OSTI ID:
- 4008513
- Journal Information:
- J. Inorg. & Nuclear Chem., Journal Name: J. Inorg. & Nuclear Chem. Vol. Vol: 18
- Country of Publication:
- Country unknown/Code not available
- Language:
- English
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