Catalytic iron-mediated triene carbocyclizations: Stereoselective five-membered ring forming carbocyclizations
Journal Article
·
· Journal of Organic Chemistry
- Univ. of Nebraska, Lincoln, NE (United States)
The full details of investigations into the regiochemistry and stereochemistry of iron-catalyzed carbocylizations of 2,7,9-decatriene derivatives to form five-membered carbocyclic ring systems are described. The roles of the allylic substituent, the alkene geometry, diene substitution, and the influence of resident stereogenic centers incorporated in the tether chain connecting the reacting 1,3-diene and alkene subunits are discussed.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 379295
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 23 Vol. 59; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
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