Hydroesterification of olefins catalyzed by Pd(OAc){sub 2} immobilized on montmorillonite
Journal Article
·
· Journal of Organic Chemistry
- Univ. of Ottawa, Ontario (Canada)
Palladium acetate immobilized on montmorillonite is an efficient catalyst for the hydroesterification of olefins with carbon monoxide and methanol, in the presence of triphenylphosphine and an acid promoter, affording branched chain esters. The reaction is regiospecific for aryl olefins as well as vinyl benzoate and regioselective for aliphatic olefins. 4 tabs.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 379229
- Journal Information:
- Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 1 Vol. 60; ISSN 0022-3263; ISSN JOCEAH
- Country of Publication:
- United States
- Language:
- English
Similar Records
Rhodium catalyzed hydroformylation of internal olefins
Synthesis of phenylallenes in the reaction of phenyl-triisopropoxytitanium with propargyl acetates catalyzed by tetrakis(triphenylphosphine)palladium
Nucleophilic substitutions of 1-alkenylcyclopropyl esters and 1-alkynylcyclopropyl chlorides catalyzed by palladium (0)
Patent
·
Mon Nov 24 23:00:00 EST 1986
·
OSTI ID:7203799
Synthesis of phenylallenes in the reaction of phenyl-triisopropoxytitanium with propargyl acetates catalyzed by tetrakis(triphenylphosphine)palladium
Journal Article
·
Mon Oct 20 00:00:00 EDT 1986
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
·
OSTI ID:6226445
Nucleophilic substitutions of 1-alkenylcyclopropyl esters and 1-alkynylcyclopropyl chlorides catalyzed by palladium (0)
Journal Article
·
Wed May 20 00:00:00 EDT 1992
· Journal of the American Chemical Society
·
OSTI ID:232151